Just published in Angew. Chem. Int. Ed. 62, e202309618 (2023): Photoinduced metallonitrene formation by N2 elimination from azide diradical ligands. Click here for more information.
Photoinduced Metallonitrene Formation by N2 Elimination from Azide Diradical Ligands Photoinduced Metallonitrene Formation by N2 Elimination from Azide Diradical Ligands
Femtosecond ultraviolet-pump/mid-infrared-probe spectroscopy reveals that singlet and triplet azide-anion diradical ligands facilitate the efficient formation of a metallonitrene from a diamagnetic azido precursor.
Formation of a metallonitrene
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